That's a misconception. The Harman curve is not something superimposed on otherwise linear reproduction to get rid of harsh treble. At least following the publications of Toole and Oliver it's almost more of a discovery than an invention.It honestly doesn't sound bright at any volume. Before the Harman curve did everyone have bleeding ears from listening to their flat systems? . What happens if the studio also uses a Harman curve at mastering time? You would end up with cascaded Harman curves in your listening room.
Put a speaker system with (anechoic) linear on-axis response and (allegedly) desirable directivity in a typical living room and (measured in the MLP) you will end up with an average response similar to the Harman curve, superimposed (tonandegree) with room resonances and reflections.
It's not a sound effect.